Francium is way too unstable to do anything with! It is extremely radioactive though so if it was possible to make a grenade I imagine it would be very explosive. There are lots of different types of radiation, and some are very deadly but can’t penetrate very far, whereas some are only lethal at high doses but penetrate and travel further.
The other problem with Francium is that very little of it occurs naturally. Scientists estimate there is never more than a gram of it in the Earth’s crust at any one time, so making a grenade of it would be very tricky!
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